The article discusses the general approaches for scandium fluoride (SCF ( 3 )) group attachment
to carbon centers. It mentions an aproach for aryl halide trifluoromethylthiolation, which …

… François Baert, Julie Colomb, Thierry Billard … Thierry Billard …

Because of its high lipophilicity, the CF 3 S group has always interested chemists. However,
strategies to introduce it into organic molecules have been, for the most part, reserved to …

Because of the unique properties of the trifluoromethoxy group, molecules bearing this moiety
will find applications in various fields, particularly in the life sciences. However, despite the …

Fluorinated moieties constitute important substituents used in many applications to modify the
properties of molecules. The action of DAST onto Ruppert's reagent yields to a not isolable …

A general method for the α‐trifluoromethylthiolation of carbonyl compounds, without
prefunctionalization, has been developed. Aldehydes, ketones, esters, amides, keto‐esters, …

Pin the tail on the alkyne: CF3S‐or CF3CF2S‐alkynes can be simply and quickly obtained
by mixing terminal alkynes with a trifluoromethanesulfenamide reagent. The reaction uses …

Trifluoromethanesulfanylamides constitute a family of easily available reagents which could
provide efficient ways to perform electrophilic trifluoromethanesulfanylation. In particular …

Trifluoromethyl thioethers (or selenoethers) are easily obtained in one pot at 0° C from
disulfides (or diselenides), commercial trifluoromethyl trimethyl silane and TBAF.

Trifluorothioacetates (CF 3 CO−S−R, from (CF 3 CO) 2 O and thiols) as well as trifluoromethanethio-
or trifluoromethaneselenosulfonates (CF 3 SO 2 −Y−R; Y = S, Se; from CF 3 SO 2 Na…