The development of an operationally simple, metal-free surface-initiated atom transfer radical
polymerization (SI-ATRP) based on visible-light mediation is reported. The facile nature of …

The scope and accessibility of sequence‐controlled multiblock copolymers is demonstrated
by direct “in situ” polymerization of hydrophobic, hydrophilic and fluorinated monomers. Key …

A versatile strategy is reported for the multigram synthesis of discrete oligomers from
commercially available monomer families, eg, acrylates, styrenics, and siloxanes. Central to this …

Introduction Alzheimer's disease (AD) is characterized by neurotoxic immuno‐inflammation
concomitant with cytotoxic oligomerization of amyloid beta (Aβ) and tau, culminating in …

The effect of dispersity on block polymer self-assembly was studied in the monodisperse
limit using a combination of synthetic chemistry, matrix-assisted laser desorption ionization …

The fabrication of well‐defined, multifunctional polymer brushes under ambient conditions
is described. This facile method uses light‐mediated, metal‐free atom‐transfer radical …

A light-mediated methodology to grow patterned, emissive polymer brushes with micron
feature resolution is reported and applied to organic light emitting diode (OLED) displays. Light …

The triple-helix stereocomplex of poly(methyl methacrylate) (PMMA) is a unique example of
a multistranded synthetic helix that has significant utility and promise in materials science …

A persistent triptycenyl sulfenic acid is used as a model for cysteine-derived and other
biologically relevant sulfenic acids in experiments which define their redox chemistry. EPR …

We report a metal-free strategy for the chain-end modification of RAFT polymers utilizing
visible light. By turning the light source on or off, the reaction pathway in one pot can be …