Abstract
Polytriazolylamines were synthesized by the copper(I)-catalyzed ligation of azides and alkynes. The C3-symmetric derivative, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
Copyright 2004 American Chemical Society
Publication types
-
Research Support, N.I.H., Extramural
-
Research Support, Non-U.S. Gov't
-
Research Support, U.S. Gov't, Non-P.H.S.
-
Research Support, U.S. Gov't, P.H.S.
MeSH terms
-
Amines / chemistry
-
Catalysis
-
Copper / chemistry*
-
Ligands
-
Molecular Structure
-
Oxidation-Reduction
-
Polymers / chemistry*
-
Triazoles / chemistry*
Substances
-
Amines
-
Ligands
-
Polymers
-
Triazoles
-
Copper